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The synthetic procedures for compounds and intermediates thereof used in this study (e.g., IN-8, IN-8a, CA-IN-8, 1a R -IN-8, 1a S -IN-8, Photocaged 1a R -IN-8, 1a R -IN-8, 1a R -IN-8, 2 -IN-8, 3 -IN-8, 4 -IN-8, 5 S -IN-8, 5 R -IN-8, 6 S,S -IN-8, 6 R,R -IN-8, 1a R -IN-7, 1a R -IN-9, 1a R -IN-10, 1a R -isoPHEN, 1b R -IN-8, 1b S -IN-8, 1c R -IN-8, 1c S -IN-8, 1d R -IN-8) are described in Supplementary Note 4

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